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Toxic metal enrichment characteristics and sources of arid urban surface soil in Yinchuan City,China |
Mingxin ZHANG1,2, Xinwei LU1,*(), Dongqi SHI1, Huiyun PAN1,3 |
1 Department of Environmental Science, School of Geography and Tourism, Shaanxi Normal University, Xi'an 710119, China 2 School of Resource and Environment, Ningxia University, Yinchuan 750021, China 3 Institute of Resources and Environment, Henan Polytechnic University, Jiaozuo 454000, China |
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Abstract To investigate the environmental quality of the urban surface soil inYinchuan City, the capital of Ningxia Hui Autonomous Region (Ningxia), China, wesampled surface soil and measured the concentrations of 8 toxic metals (Pb, Cr, Cu, Zn, Co, Bi, Ni and V) using X-ray fluorescence spectrometry. The enrichment characteristics and sources of these toxic metals in the soil were analyzed by the enrichment factor (EF) and multivariate statistical analysis. The results showed that the mean concentrations of these toxic metals in the soil samples were 25.0, 109.1, 16.8, 26.0, 37.2, 2.7, 25.3 and 59.9 mg/kg for Pb, Cr, Cu, Zn, Co, Bi, Niand V, respectively, which were 1.2, 1.8, 0.8, 0.4, 3.2, 8.7, 0.7 and 0.8 times of the corresponding background values of Ningxia soil, respectively. The variations of Pb, Zn, Co, Biand Ni concentrations in the surface soil of Yinchuan were larger than those of the other metals.Our results also showed that the toxic metals investigated in the soil had different enrichment levels. Both Co and Bi were significantly enriched, whereas Cr was only moderatelyenriched in the soil. There was a deficiency or minimal enrichment of the other toxic metals in the soil. Source analysis results based on the concentration, enrichment characteristics and multivariate statistical analysis indicated that Cr, V and Ni originated from a combination of fossil fuel combustion, traffic pollution and natural occurrence.Pb, Cu and Zn were predominantly derived from natural and traffic sources, while Co and Bi primarily originated from construction sources.
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Received: 31 May 2017
Published: 10 August 2018
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[1] | Acosta JA, Faz A, Martínez-Martínez S, et al.2011. Enrichment of metals in soils subjected to different land uses in a typical Mediterranean environment(Murcia city, southeast Spain). Applied Geochemistry, 26(2): 405-414. | [2] | Andersson M, Ottesen RT, Langedal M.2010. Geochemistry of urban surface soils-Monitoring in Trondheim, Norway. Geoderma, 156(3-4): 112-118. | [3] | Banat KM, Howari FM, Al-Hamad AA.2005. Heavy metals in urban soils of central Jordan: Should we worry about their environmental risks? Environmental Research, 97(3): 258-273. | [4] | Batjargal T, Otgonjargal E, Baek K, et al.2010. Assessment of metals contamination of soils in Ulaanbaatar, Mongolia. Journal of Hazardous Materials, 184(1-3): 872-876. | [5] | Chen H, Lu XW, Li LY, et al.2014. Metal contamination in campus dust of Xi'an, China: A study based on multivariate statistics and spatial distribution. Science of the Total Environment, 484: 27-35. | [6] | Chen XD, Lu XW, Yang G.2012. Sources identification of heavy metals in urban topsoil from inside the Xi'an Second Ringroad, NW China using multivariate statistical methods. CATENA, 98: 73-78. | [7] | China National Environmental Monitoring Center(CNEMC). 1990. The Background Values of Elements in Chinese Soils. Beijing: Environmental Science Press of China, 338-379. (in Chinese) | [8] | Christoforidis A, Stamatis N.2009. Heavy metal contamination in street dust and roadside soil along the major national road in Kavala's region, Greece. Geoderma, 151(3-4): 257-263. | [9] | De Miguel E, De Grado M J, Llamas JF, et al.1998. The overlooked contribution of compost application to the trace element load in the urban soil of Madrid(Spain). Science of the Total Environment, 215(1-2): 113-122. | [10] | Facchinelli A, Sacchi E, Mallen L.2001. Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. Environmental Pollution, 114(3): 313-324. | [11] | Han YM, Du PX, Cao JJ, et al.2006. Multivariate analysis of heavy metal contamination in urban dusts of Xi'an, Central China. Science of the Total Environment, 355(1-3): 176-186. | [12] | Hewitt CN, Rashed MB.1990. An integrated budget for selected pollutants for a major rural highway. Science of the Total Environment, 93: 375-384. | [13] | Imperato M, Adamo P, Naimo D, et al.2003. Spatial distribution of heavy metals in urban soils of Naples city(Italy). Environmental Pollution, 124(2): 247-256. | [14] | Lee CSL, Li XD, Shi WZ, et al.2006. Metal contamination in urban, suburban, and country park soils of Hong Kong: a study based on GIS and multivariate statistics. Science of the Total Environment, 356(1-3): 45-61. | [15] | Lu SG, Bai SQ.2006. Study on the correlation of magnetic properties and heavy metals content in urban soils of Hangzhou City, China. Journal of Applied Geophysics, 60(1): 1-12. | [16] | Lu XW, Li LY, Wang LJ, et al.2009. Contamination assessment of mercury and arsenic in roadway dust from Baoji, China. Atmospheric Environment, 43(15): 2489-2496. | [17] | Lu XW, Wang LJ, Li LY, et al.2010. Multivariate statistical analysis of heavy metals in street dust of Baoji, NW China. Journal of Hazardous Materials, 173(1-3): 744-749. | [18] | Lu XW, Wu X, Wang YW, et al.2014. Risk assessment of toxic metals in street dust from a medium-sized industrial city of China. Ecotoxicology and Environmental Safety, 106: 154-163. | [19] | Lu Y, Gong ZT, Zhang GL, et al.2003. Concentrations and chemical speciations of Cu, Zn, Pb and Cr of urban soils in Nanjing, China. Geoderma, 115(1-2): 101-111. | [20] | Maas S, Scheifler R, Benslama M, et al.2010. Spatial distribution of heavy metal concentrations in urban, suburban and agricultural soils in a Mediterranean city of Algeria. Environmental Pollution, 158(6): 2294-2301. | [21] | Madany IM, Akhter MS, Jowder OA A.1994. The correlations between heavy metals in residential indoor dust and outdoor street dust in Bahrain. Environment International, 20(4): 483-492. | [22] | Manta DS, Angelone M, Bellanca A, et al.2002. Heavy metals in urban soils: a case study from the city of Palermo(Sicily), Italy. Science of the Total Environment, 300(1-2): 229-243. | [23] | Meza-Figueroa D, De La O-Villanueva M, De La Parra ML.2007. Heavy metal distribution in dust from elementary schools in Hermosillo, Sonora, México. Atmospheric Environment, 41(2): 276-288. | [24] | Mielke HW, Gonzales CR, Smith MK, et al.1999. The urban environment and children's health: soils as an integrator of lead, zinc, and cadmium in New Orleans, Louisiana, U.S.A. Environmental Research, 81(2): 117-129. | [25] | Möller A, Müller HW, Abdullah A, et al.2005. Urban soil pollution in Damascus, Syria: concentrations and patterns of heavy metals in the soils of the Damascus Ghouta. Geoderma, 124(1-2): 63-71. | [26] | Morton-Bermea O, Hernández-álvarez E, González-Hernández G, et al.2009. Assessment of heavy metal pollution in urban topsoils from the metropolitan area of Mexico City. Journal of Geochemical Exploration, 101(3): 218-224. | [27] | Ngole-Jeme VM.2016. Heavy metals in soils along unpaved roads in south west Cameroon: Contamination levels and health risks. Ambio, 45(3): 374-386. | [28] | Ningxia Municipal Bureau of Statistics(NMBS). 2013. Ningxia Statistical Yearbook. Beijing: China Statistics Press, 31-50. (in Chinese) | [29] | Papa S, Bartoli G, Pellegrino A, et al.2010. Microbial activities and trace element contents in an urban soil. Environmental Monitoring and Assessment, 165(1-4): 193-203. | [30] | Saeedi M, Li LY, Salmanzadeh M.2012. Heavy metals and polycyclic aromatic hydrocarbons: Pollution and ecological risk assessment in street dust of Tehran. Journal of Hazardous Materials, 227-228: 9-17. | [31] | Shi GT, Chen ZL, Xu SY, et al.2008. Potentially toxic metal contamination of urban soils and roadside dust in Shanghai, China. Environmental Pollution, 156(2): 251-260. | [32] | Sun YB, Zhou QX, Xie XK, et al.2010. Spatial, sources and risk assessment of heavy metal contamination of urban soils in typical regions of Shenyang, China. Journal of Hazardous Materials, 174(1-3): 455-462. | [33] | Tume P, Bech J, Reverter F, et al.2011. Concentration and distribution of twelve metals in central Catalonia surface soils. Journal of Geochemical Exploration, 109(1-3): 92-103. | [34] | Wang W, Lai YS, Ma YY, et al.2016. Heavy metal contamination of urban topsoil in a petrochemical industrial city in Xinjiang, China. Journal of Arid Land, 8(6): 871-880. | [35] | Wang YQ, Bai YR, Wang JY.2014. Distribution of soil heavy metal and pollution evaluation on the different sampling scales in farmland on Yellow River irrigation area of Ningxia: a case study in Xingqing county of Yinchuan city. Environmental Science, 35(7): 2714-2720. (in Chinese) | [36] | Wilcke W, Müller S, Kanchanakool N, et al.1998. Urban soil contamination in Bangkok: heavy metal and aluminium partitioning in topsoils. Geoderma, 86(3-4): 211-228. | [37] | Xia XH, Chen X, Liu RM, et al.2011. Heavy metals in urban soils with various types of land use in Beijing, China. Journal of Hazardous Materials, 186(2-3): 2043-2050. | [38] | Yang ZP, Lu WX, Long YQ, et al.2011. Assessment of heavy metals contamination in urban topsoil from Changchun City, China. Journal of Geochemical Exploration, 108(1): 27-38. | [39] | Zhang CS.2006. Using multivariate analyses and GIS to identify pollutants and their spatial patterns in urban soils in Galway, Ireland. Environmental Pollution, 142(3): 501-511. | [40] | Zhang GL, Yang FG, Zhao YG, et al.2005. Historical change of heavy metals in urban soils of Nanjing, China during the past 20 centuries. Environment International, 31(6): 913-919. | [41] | Zhao N, Lu XW, Chao SG.2016. Risk assessment of potentially toxic elements in smaller than 100-μm street dust particles from a valley-city in northwestern China. Environmental Geochemistry and Health, 38(2): 483-496. |
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